Rodd's chemistry of carbon compounds. Volume II, Alicyclic compounds; Part C, Polycyclic compounds, excluding steroids (Coffey, S.)

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Chemistry of Strained Polycyclic Compounds —vi1,2

The base induced homoketonization of bridgehead cubane alcohol 10, homocubane alcohol 1 and acetate 7, and 1,3-bishomocubane alcohols 13 and 17 has been studied. Under protic conditions, homocubane alcohol 1 and acetate 7 are converted quantitatively into half cage ketones 3 and 8, respectively. by exclusive cleavage of the C4— C7 bond. Similarly, homoketonization of 1,3-bishomocubane alcohols ...

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ژورنال

عنوان ژورنال: Journal of Chemical Education

سال: 1970

ISSN: 0021-9584,1938-1328

DOI: 10.1021/ed047pa304.2